CAS:19231-06-2 bis(p-methoxyphenyl)iodonium bromide
NAME:bis(p-methoxyphenyl)iodonium bromide CAS:19231-06-2 MF:C14H14BrIO2 MW:421.06823 PURITY:98%
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Material Chemistry
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Product introduction
| NAME | bis(p-methoxyphenyl)iodonium bromide |
| CAS | 19231-06-2 |
| MF | C14H14BrIO2 |
| MW | 421.06823 |
| DENSITY | 1.82 |
| MP | 190-192 °C |
| EINECS | 242-899-4 |
| STORAGE | Keep in dark place,Inert atmosphere,Room temperature |
Description
Synthesis Analysis
The synthesis of bis(p-methoxyphenyl)iodonium salts, including bromide, involves the use of diaryliodonium salts. McKerrow, Al‐Rawi, and Brooks (2012) demonstrated the arylation of α-amino acid methyl esters using bis[(3'-methoxycarbonyl)phenyl]iodonium bromide and related compounds, yielding good to high yields of N-aryl α-amino acids while maintaining the chiral integrity of the amino acids throughout the reaction sequence. The structures of these compounds were confirmed by IR, 1H, and 13C NMR spectroscopy, in addition to CHN microanalysis or high-resolution mass spectrometry
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